Factory supply 3-Butyn-1-ol solution/ CAS:927-74-2/ wholesale price

Factory supply 3-Butyn-1-ol solution/ CAS:927-74-2/ wholesale price.

 

Buy 3-Butyn-1-ol solution (CAS 927-74-2). Factory supply 3-Butyn-1-ol solution/ CAS:927-74-2/ wholesale price. 2-Methylbut-3-yn-2-ol is the organic compound with the formula HC2C(OH)Me2 (Me = CH3). A colorless liquid, it is classified as an alkynyl alcohol.

3-Butyn-1-ol solution factory suppliers

It arises from the condensation of acetylene and acetone. The addition can be promoted with base or with Lewis acid catalysts.  is produced on an industrial scale as a precursor to terpenes and terpenoids. Buy 3-Butyn-1-ol solution (CAS 927-74-2)

3-Butyn-1-ol for sale wholesale

2-Methylbut-3-yn-2-ol also is used as a monoprotected version of acetylene. For example, after arylation at carbon, the acetone can be removed with base: Buy 3-Butyn-1-ol solution (CAS 927-74-2)

HC2C(OH)Me2 + ArX + base → ArC2C(OH)Me2 + [Hbase]X
ArC2C(OH)Me2 → ArC2H + OCMe2

In this regard, 2-methylbut-3-yn-2-ol is used similarly to trimethylsilylacetylene.

Keywords 3-Butyn-1-ol for sale

Quick Details 3-Butyn-1-ol for sale
  • ProName: 3-Butyn-1-ol
  • CasNo: 927-74-2
  • Molecular Formula: C4H6O
  • Appearance: colorless or slightly yellow transparent
  • Application: Pharma Intermediate
  • DeliveryTime: Within 2 weeks after order confirmation
  • PackAge: 3-Butyn-1-Ol is normally packed in 15…
  • Port:china
  • ProductionCapacity: 10000 Metric Ton/Year
  • Purity: ≥98.5%
  • Storage: Store in cool and dry place, away from…
  • Transportation: By sea
  • LimitNum: 5 Metric Ton
  • CAS: 927-74-2
  • MF: C4H6O
  • Buy 3-Butyn-1-ol solution (CAS 927-74-2)
3-BUTYN-1-OL
PRODUCT IDENTIFICATION
CAS NO. 927-74-2
EINECS NO. 213-161-9
FORMULA HC��CCH2CH2OH
MOL WT. 70.09
H.S. CODE 2905.29.9000
UN NO. 1986
SYNONYMS 3-Butynol; 3-Butynyl alcohol; 4-Hydroxy-1-butyne; But-3-yn-1-ol;
1-Butyn-4-ol; 2-Hydroxyethylacetylene;
SMILES C(C#C)CO
CLASSIFICATION Alkyne, Acetylenic alcohol,  Propargylic alcohol.
PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE clear liquid
MELTING POINT < -63 C
BOILING POINT 128 – 129 C
SPECIFIC GRAVITY 0.926
SOLUBILITY IN WATER Soluble
SOLVENT SOLUBILITY Soluble in alcohols and organic solvents. Immiscible with aliphatic hydrocarbon solvents.
pH
VAPOR DENSITY 2.4
log Pow 0.07(Octanol-water)
HENRY LAW CONSTANT 1.23E-11 (atm-m3/mole at 25 C)
NFPA RATINGS Health: 2; Flammability: 3; Reactivity: 0
REFRACTIVE INDEX
FLASH POINT 36 C
STABILITY Stable under ordinary conditions.
GENERAL DESCRIPTION & EXTERNAL LINKS
Alkynyl substrate used in a study of a palladium-catalyzed coupling with -tetrionic acid bromide leading to alkynyl substituted furanones in good yield. Synthon for preparation of oxygen-containing heterocycles and protected esters of s-Hydroxy-L-isoleucine.

Acetylenic alcohol containing -OH and triple bond can be applicable to;

  • Corrosion inhibitor formulation
  • Metal complex solution
  • Solvent stabilizer
  • Biodegradable chemical intermediate to make pesticides, biocides and pharmaceuticals.
  • Acetylene chemistry and reagents

Alkynes contain a highly versatile functional group that may be utilized for numerous reactions such as electrophilic additions of hydrogen, halogens, hydrogen halides, or water; metathesis; hydroboration; oxidative cleavage; C-C coupling; and cycloadditions. Terminal alkynes may be transformed into metal acetylides and can then be submitted to nucleophilic substitution with alkyl halides, forming new C-C bonds, or nucleophilic addition, e.g., the Favorskii reaction.

Material Safety Data Sheet

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SALES SPECIFICATION
APPEARANCE clear liquid
CONTENT 98.0% min
WATER 0.5% max
COLOR, APHA 20 max
TRANSPORTATION
PACKING
HAZARD CLASS 3 (Packing Group: II)
UN NO. 1987
OTHER INFORMATION
Hazard Symbols: XI, Risk Phrases: 10-36/37/38, Safety Phrases: 9-16-24/25-33
GENERAL DESCRIPTION OF ALKYNE
Alkynes are aliphatic hydrocarbons that have one or more carbon-carbon triple bonds. The general structure of the alkyne hydrocarbons with one triple bond is CnH2n-2. They are insoluble in water but easily soluble in common organic solvents of low polarity. The features of alkynes in chemical synthesis is due to the acidity of hydrogen atoms bonded to triply bonded carbons as well as the triple bonds themselves. Addition reactions are typical in alkyne reactions; halogenation, hydrogenation, hydrohalogenation, hydration, oxidative cleavage,  nitrile formation and acidity of terminal alkynes. Polymerisation and substitution reactions are also useful in chemical synthesis.

  • Addition Reactions
    • Catalytic Hydrogenation by Pt and Pd hydrogenation catalysts to yeild alkanes without isolation of alkene intermediates.
    • Catalytic Hydrogenation by Lindlar’s catalyst to yeild cis- or trans- alkenes without further reduction to alkanes
    • Addition by Electrophilic Reagents
      • Addition of halides (chlorine, bromine, iodine) to yield dihalogen substituted alkanes at the solid bond site
      • Addition of hydrogen halides (HCl, HBr, HI) to yield monohalogen substituted alkenes or dihalogen substituted alkanes
    • Hydration of alkynes to yield ketone products through enol tautomer intermediate stage, whereas the hydration of solid bonds gives alcohol products (exceptionally acetylene yields acetaldehyde ).
    • Hydroboration by disiamylborane to yield ketones or aldehydes
    • Oxidation cleavages of the triple-bond to give carboxylic acid products with oxidizing agents (potassium permanganate and ozone)
  • Nucleophilile Addition by sp-hybrid carbon atoms of the triple-bond render alkynes (nitrile formation)
  • Nucleophilile Reduction by solutions of sodium in liquid ammonia to trans-alkenes

The name of all alkynes end in “-yne” adding a prefix to indicate the location of the triple bond in the molecule.

COMPOUND SYNONYM FORMULA CAS RN M.P (C) B.P (C)
Ethyne Acetylene C2H2 74-86-2 -84.0 -28
Propyne Methyl acetylene C3H 74-99-7 -103 -23
1,3-Butadiyne Diacetylene C4H2 460-12-8   10
1-Butyne Ethyl acetylene C4H6 107-00-6 -125.7 8
2-Butyne Crotonylene C4H6 503-17-3 -32.2 27
1,3-Pentadiyne   C5H4 4911-55-1    
3-Penten-1-yne Propenyl acetylene C5H6 2206-23-7    
2-Methyl-1-buten-3-yne Isopropenyl acetylene C5H6 78-80-8 -113 32
1-Penten-3-yne Methyl vinyl acetylene C5H6 646-05-9    
1-Penten-4-yne Allyl acetylene C5H6 871-28-3    
2-Pentyne Ethyl methyl acetylene C5H8 627-21-4 -109 56
3-Methyl-1-butyne Isopropyl acetylene C5H8 598-23-2 -89.7 26
1-Pentyne Propyl acetylene C5H8 627-19-0 -106 40
3-Hexyne Diethyl acetylene C6H10 928-49-4 -103 81
2-Hexyne Methyl propyl acetylene C6H10 764-35-2 -89.1 84
4-Methyl-1-pentyne Isobutyl acetylene C6H10 7154-75-8 -105 61
1-Hexyne Butyl acetylene C6H10 693-02-7 -131.9 71
3-Methyl-1-pentyne sec-Butyl acetylene C6H10 922-59-8   58
4-Methyl-2-pentyne Isopropyl methyl acetylene C6H10 21020-27-9 -110 73
3,3-Dimethyl-1-butyne tert-Butyl acetylene C6H10 917-92-0 -78.2 38
1,5-Hexadiyne Dipropargyl C6H6 628-16-0 -6 86
1,4-Hexadiyne   C6H6 10420-91-4   79
1,5-Hexadien-3-yne Divinyl acetylene C6H6 821-08-9  
1-Hexen-3-yne Ethyl vinyl acetylene C6H8 13721-54-5   84
4-Methyl-2-hexyne sec-Butyl methyl acetylene C7H12 20198-49-6 -108 100
2-Methyl-3-hexyne Isopropyl ethyl acetylene C7H12   -117 95
5-Methyl-2-hexyne Isobutyl methyl acetylene C7H12 53566-37-3 -93 102
3-Ethyl-1-pentyne   C7H12     84
1-Heptyne n-Pentyl acetylene C7H12 628-71-7 -81 100
4,4-Dimethyl-2-pentyne tert-Butyl methyl acetylene C7H12 999-78-0   83
3-Heptyne Ethyl propyl acetylene C7H12 2586-89-2 -131 107
4,4-Dimethyl-1-pentyne Neopentyl acetylene C7H12   -75 78
2-Heptyne n-Butyl methyl acetylene C7H12 1119-65-9   112
1,6-Heptadiyne   C7H8 2396-63-6   108
1,7-Octadiyne   C8H10 871-84-1   135
2,6-Octadiyne   C8H10 764-73-8    
Cyclooctyne   C8H12 1781-78-8    
4-Octyne Dipropyl acetylene C8H14 1942-45-6 -102.5 132
1-Octyne n-Hexyl acetylene C8H14 629-05-0 -79.3 126
3-Octyne n-Butyl ethyl acetylene C8H14 15232-76-5 -104 133
2-Octyne n-Pentyl methyl acetylene C8H14 2809-67-8 -61.6 138
1,8-Nonadiyne   C9H12 2396-65-8 -21  
Cyclononyne   C9H14 6573-52-0    
1-Nonyne n-Heptyl acetylene C9H16 3452-09-3 -50 151
3-Nonyne Methyl n-pentyl acetylene C9H16 20184-89-8   157
2-Nonyne n-Hexyl methyl acetylene C9H16 19447-29-1   162
4-Nonyne n-Butyl propyl acetylene C9H16 20184-91-2    
Cyclodecyne   C10H16 3022-41-1    
5-Decyne Di-n-butyl acetylene C10H18 1942-46-7 -73  
3-Decyne Ethyl n-hexyl acetylene C10H18 2384-85-2   179
1-Decyne n-Octyl acetylene C10H18 764-93-2 -44 174
2,2,5,5-Tetramethyl-3-hexyne Di-tert-butyl acetylene C10H18 17530-24-4    
1-Undecyne n-Nonyl acetylene C11H20 2243-98-3 -25 195
6-Dodecyne Di-n-pentyl acetylene C12H22 6975-99-1    
1-Dodecyne n-Decyl acetylene C12H22 765-03-7 -19 225
1-Tridecyne n-Undecyl acetylene C13H24 26186-02-7 -5 234
1-Tetradecyne n-Dodecyl acetylene C14H26 765-10-6   252
1-Pentadecyne n-Tridecyl acetylene C15H28 765-13-9 10 269
1-Hexadecyne n-Tetradecyl acetylene C16H30 629-74-3 25 285
1-Heptadecyne n-Pentadecyl acetylene C17H32 26186-00-5 22 300
1-Heptadecyne n-Pentadecyl acetylene C17H32 26186-00-5 22 300
2-Octadecyne   C18H34     325
1-Octadecyne   C18H34 629-89-0    
1-Nonadecyne   C19H36   33 329
1-Eicosyne 1-Icosyne C20H38   36 342

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